Safety Data Sheet

EURONDA S.P.A.
ICE SPRAY
Revision No. 2.0
Revision date 28/05/2013
Printed on 28/05/2013
Page No. 1/11
Safety Data Sheet
SECTION 1 Identification of the substance/mixture and the of company/undertaking
1.1. Identification of the product
Code:
Product Name
FR030
®
MONOART GHIACCIO SPRAY
ICE SPRAY
KÄLTESPRAY
1.2. Intended and unintended use of the substance or mixture
Description/Use
Dental prosthesis production aid
1.3. Information on the supplier of the Safety Data Sheet
Company Name:
Address
City and Country
EURONDA S.P.A.
Via dell' Artigianato 7
Montecchio Precalcino (VI)
36030
tel. 0039 0445329811
email of the person
in charge of the safety data sheet
Product Marketing Manager:
[email protected]
EURONDA S.P.A
1.4. Emergency telephone number
For urgent information please contact
Poison Centres: 0039 0266101029 Ospedale Niguarda Ca’ Granda
SECTION 2 Hazards Identification.
2.1. Classification of the substance or mixture.
The product is classified as hazardous under Council Directive 1999/45 and Regulation (EC) 1272/2008 (CLP) (as amended). The product therefore
requires a safety data sheet according to Regulation (EC) 1907/2006 as amended.
Any additional information concerning risks for human health and/or the environment is included in sections 11 and 12 of this safety sheet.
2.1.1. Directive (EC) 1272/2008 (CLP) as amended.
Hazard classification and statements:
Flammable Aerosol 1
H222
2.1.2. Directives 67/547/EEC and 1999/45/EC as amended.
Hazard symbols:
F+
R Phrases:
12
The complete text of the risk phrases (R) and hazard statements (H) are provided in section 16 of the sheet.
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2.2. Label elements.
Hazard labelling under Regulation (EC) 1272/2008 (CLP) as amended.
Hazard symbols:
Warnings:
Hazard statements:
H222
Hazard
Highly flammable aerosol.
Precautionary recommendations:
No precautionary recommendations are applicable as they are redundant with the mandatory precautionary statements required by Directive
(EC) 75/324. (see section 15.1)
2.3. Other hazards.
Although the product does not contain irritant or corrosive substances, it can cause cold burns on the skin if sprayed from a short distance.
SECTION 3 Composition/information on the ingredients
3.2. Mixtures.
It contains:
Identification.
Conc.%.
Classification under
Directive 67/548/EEC.
Classification under Directive
1272/2008 (CLP).
58
F+ R12, Note U
Flammable Gas 1 H220, Note U
39
F+ R12, Note C U
Flammable Gas 1 H220, Note C U
3
F R11
Flammable Liquid 2 H225
PROPANE
CAS. 74-98-6
EC. 200-827-9
INDEX. 601-003-00-5
BUTANE
CAS. 106-97-8
EC. 203-448-7
INDEX. 601-004-00-0
ETHANOL
CAS. 64-17-5
EC. 200-578-6
INDEX. 603-002-00-5
The complete text of the risk phrases (R) and hazard statements (H) is provided in section 16 of the sheet.
( T+ = Highly Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Comburent(O), E = Explosive(E), F+ = Extremely
flammable(F+), F = Highly flammable(F), N = Hazardous for the Environment(N) )
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SECTION 4 First Aid Measures.
4.1. Description of first aid measures.
The following general measures shall be adopted as necessary:
INHALATION: Accompany the patient to an area with fresh air. Give artificial respiration if breathing has stopped. Consult a doctor immediately.
INGESTION: The product is not specifically hazardous, but the temperature in the zone exposed to sprayed gas could drop quite considerably
generating cold burn risks. Seek medical advice immediately. Never give anything by mouth if the patient is unconscious.
SKIN CONTACT: The product is not specifically hazardous, but the temperature in the zone exposed to sprayed gas could drop quite considerably
generating cold burn risks. In cases of exposure it is recommended to irrigate the skin with warm water for 10 minutes. In case of irritation or burns, seek
medical advice.
EYE CONTACT: the product is not specifically hazardous, but the temperature in the zone exposed to sprayed gas could drop quite considerably
generating cold burn risks. Irrigate copiously under warm running water holding the lids apart. Seek medical advice if irritation or sight problems persist.
4.2. Most important symptoms and effects, both acute and delayed.
No episodes of damage to health have been attributed to the products.
4.3. Indication of any immediate medical attention and special treatment needed.
Information unavailable.
SECTION 5 Fire-fighting measures.
5.1. Extinguishing media.
SUITABLE EXTINGUISHING MEDIA
Traditional extinguishing media should be used: carbon dioxide, misted water/foam and powder if solid/liquid materials are involved in the fire.
UNSUITABLE EXTINGUISHING MEDIA:
Water jets
5.2. Special hazards arising from the substance or mixture.
HAZARDS DUE TO EXPOSURE IN FIRE BREAKOUTS
If the aerosol containers overheat, they can deform, explode and be hurled at a considerable distance. Wear protection helmets before approaching the
fire. Do not inhale combustion fumes.
5.3. Special recommendations for fire-fighters.
GENERAL INFORMATION
Spray the containers with water to cool them down and prevent decomposition of the product or the development of substances which are a potential
health hazard. Always wear complete fire protection equipment.
EQUIPMENT
Standard fire-fighting attire, self-contained open circuit compressed-air-operated breathing apparatus (EN 317) flameproof overalls (EN 469) flameproof
gloves (EN 659) and fire-fighter boots (HO A29 or A 30)
SECTION 6 Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures.
For those who do not intervene directly: evacuate the incident zone immediately and wait for the emergency squad to cordon off the release area.
For those who intervene directly: eliminate all sources of heat and ignition (cigarettes, flames, sparks etc.) from the accidental release area.
Wear the protective equipment listed in section 8.2 of this document before commencing any form of intervention. Ventilate the incident area until the air
is clean.
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For those who do not intervene directly: evacuate the incident zone immediately and wait for the emergency squad to cordon off the release area.
For those who intervene directly: eliminate all sources of heat and ignition (cigarettes, flames, sparks etc.) from the accidental release area.
Wear the protective equipment listed in section 8.2 of this document before commencing any form of intervention. Ventilate the incident area until the
air is clean.
6.2. Environmental precautions.
Prevent dispersion into the environment.
6.3. Methods and materials for containment and collection.
Ventilate the area of accidental release. Disposal of the contaminated material must be performed in accordance with the provisions under section 13.
6.4. Reference to other sections.
Any information concerning personal protective equipment and disposal procedures are illustrated in sections 8 and 13.
SECTION 7 Handling and storage.
7.1. Precautions for safe handling.
Avoid any electrostatic charge accumulation. Do not spray on flames or incandescent objects. Vapours can explode and ignite. It is therefore necessary
to prevent any accumulation by opening doors and windows to create a draught. Do not eat, drink or smoke whilst using the products. Do not inhale the
aerosols.
7.2. Conditions for safe storage, including any incompatibilities.
Store in well ventilated place, away from direct sunlight at temperatures below 50°C and away from sources of ignition.
7.3. Particular end use
Information unavailable.
SECTION 8 Exposure control/personal protection
8.1. Control parameters.
Reference Standards:
Italy
OEL EU
TLV-ACGIH
Legislative Decree No. 81 of April 9, 2008
Dir. 91/332/EC; Dir. 96/94/EC; Dir. 2000/39/EC; Dir. 2004/37/EC; Dir. 2006/15/EC; Dir.
2009/161/EC
ACGIH 2012
PROPANE
Threshold limit value.
Type
Form
TWA/8h
mg/m3
TLV-ACGIH
STEL/15min
ppm
1000
mg/m3
ppm
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BUTANE
Threshold limit value.
Type
Form
TLV
CH
TWA/8h
STEL/15min
mg/m3
ppm
1900
800
TLV-ACGIH
mg/m3
ppm
1000
ETHANOL
Threshold limit value.
Type
Form
TWA/8h
mg/m3
STEL/15min
ppm
TLV-ACGIH
mg/m3
ppm
1884
1000
Key:
(C) = CEILING ; INALAB = Inhalable fraction ; RESPIR = Breathable fraction ; TORAC = Toracic Fraction.
VND = hazard identified but no DNEL/PNEC available ; NEE = no exposure envisaged ; NHI = no hazard identified.
8.2. Exposure controls.
Given that the use of suitable technical measures should always have priority over personal protective equipment, the workplace should always be well
ventilated with an effective air exchange system. All personal protective equipment must meet the requirements of the regulatory standards indicated
below.
HAND PROTECTION
Not specifically necessary due to the type of use. However, if there is a risk of cold burns caused by contact with the sprayed product, use the special
category lll diathermal gloves (ref. Standard EN 511).
EYE PROTECTION
It is recommended to wear airtight protective goggles (ref. Standard EN 166)
SKIN PROTECTION
Not specifically necessary due to the type of use. However, if there is a risk of cold burns caused by contact with the sprayed product, use long-sleeved
work overalls. Where foreseen by the Risk assessment at the workplace, wear work overalls for protection against category lll cryogenic risks (EN 511 420 - 388) and category lll professional safety boots (ref. Directive 89/686/EEC and Standard EN 344). Wash with soap and water after removing all
protective clothing.
RESPIRATORY PROTECTION
If the limit values (were available) are exceeded by one or more of the substances present in the product, referring to daily exposure at the work place or
a fraction established by the protection and prevention service, wear a category Ill type A semi-facial filter (ref. standards EN 141/EN 143).
The use of respiratory protection equipment, such as masks as indicated above, is necessary if there are no technical means used to limit occupational
exposure. The protection provided by masks is rather limited.
If the substance in question is odourless or its odour detection threshold is above the relative exposure limits and in all emergency situations, or when
the exposure levels are unknown or the concentration of oxygen in the work environment is below 17% in volume, always wear self-contained open
circuit compressed-air-operated breathing apparatus (ref. standard EN 137) or external air breathing apparatus for use with full-face masks, half-face
masks or a mouthpiece (ref. standard EN 138).
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SECTION 9 Physical and chemical properties.
9.1. Main information on physical and chemical properties.
Physical Form:
aerosol
Colour
Not available.
Odour
characteristic
Odour detection threshold.
Not available.
pH.
(Not applicable (given it is an aerosol).
Melting point or freezing point.
Not available.
Initial boiling point.
-161°C (registration dossier available on the ECHA site)
Boiling point range.
Not available.
Flash point.
-97°C.
Evaporation rate
Not available.
Flammability of solids and gas
Not available.
Lower flammability limit.
1.5% (V/V).
Upper flammability limit.
10.9% (V/V).
Lower explosive limit.
Not available.
Upper explosive limit.
Not available.
Vapour pressure.
Not available.
Vapour density.
Not available.
Relative density.
Not available.
Solubility
Slightly soluble in water.
N-octanol/water partition coefficient:
Not available.
Auto igniting temperature.
365°C.
Decomposition temperature.
Not available.
Viscosity
Not available.
Explosive properties
Not available.
Oxidising properties
Not applicable (no chemical groups associated to oxidising properties present in the
Molecule. See Annex I reg. 1272/2008 section 2.1.3.4).
9.2. Further information.
VOC (Directive 1999/13/EC)
VOC (volatile carbon):
100.00%
81.12%
SECTION 10 Stability and reactivity
10.1. Reactivity.
The product is mainly composed of gaseous hydrocarbons. They have exothermic and violent reactions in the presence of a comburent and an igniter.
10.2. Chemical stability.
The product is stable under normal handling and storage conditions.
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10.3. Possibility of hazardous reactions.
No hazardous reactions are contemplated under normal handling and storage conditions.
10.4. Conditions to avoid.
Avoid overheating and physical shaking of the product container as it is pressurised.
10.5. Materials to avoid.
Strong reducers and oxidising agents, strong acids and base agents, high temperature materials that can compromise the integrity of the aerosol
container and allow the flammable content to escape.
10.6. Hazardous decomposition products.
Combustion of the product mainly releases carbon dioxide and water, but in incorrect combustion conditions, it can also release toxic pyrolysis products
and carbon monoxide.
SECTION 11 Toxicological information.
11.1. Information on toxicological effects.
There is no toxicological information available on the product itself. However, the toxicological information on the individual components can be found
below.
PROPANE
CL50 (Inhalation). 1237 mg/l/2h (species: mouse)
BUTANE
CL50 (Inhalation). 1237 mg/l/2h (species: mouse)
Source: Aviado DM, Zakheri S and Watanabe T, Non-Fluorinated Propellants and Solvents for Aerosols, chapter 6 pp 61-72. CRC Press, Cleveland,
Ohio, USA; 1977
ETHANOL
DL50 (Oral). 1501 mg/kg (species: rat)
CL50 (Inhalation). 5,9 mg/l/6h (species: rat)
SECTION 12 Ecological Information
Apply standard practices for good workmanship when using the product, preventing its dispersal into the environment.
There is no toxicological information available on the product itself. However, the toxicological information on the individual components can be found
below.
12.1. Toxicity.
Information unavailable.
12.2. Persistence and biodegradability.
Information unavailable.
12.3. Bioaccumulative potential.
Information unavailable.
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12.4. Mobility in soil.
Information unavailable.
12.5. Results of PBT and vPvB assessment.
Based on the data available, the product does not contain PBT or vPvB substances in percentages over 0.1%.
12.6. Other adverse effects.
Information unavailable.
SECTION 13 Disposal considerations
13.1. Waste treatment methods.
Reuse where possible. Residual products are classified as hazardous special waste. The hazardous level of the waste that this product contains must
be assessed according to applicable regulations in force.
Authorised waste management enterprises shall be appointed to dispose of waste, in accordance with all national and local regulations in force.
Waste transportation may be subject to ADR requirements.
CONTAMINATED PACKAGING
Contaminated packaging must be sent for recovery or disposal in accordance with national waste management regulations.
SECTION 14 Transport Information.
Transport is to be provided by vehicle authorised to transport hazardous waste in accordance with the requirements of the ADR in force and the national
provisions in force. Products shall be transported in their original packaging and, in any case, in packaging consisting of materials that are resistant to
the contents and will not generate hazardous reactions with the same. Operators assigned to loading and unloading hazardous goods must receive
suitable training on the risks of the specific substance or mixture and any special procedures to be implemented during emergency situations.
Road or rail transport:
ADR/RID Classification:
2
Packing Group:
-
Label:
2.1
Kemler No.:
--
Limited Quantity.
1L
Restriction code in tunnels.
(D)
Technical name:
AEROSOL
UN:
1950
UN:
1950
Sea transport:
IMO Classification:
2.1
Packing Group:
-
Label:
2.1
EMS:
F-D, S-U
Marine Pollutant.
NO
Proper Shipping Name:
AEROSOLS
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Air transport:
IATA:
2
UN:
1950
Packing Group:
-
Label:
2.1
203
Maximum quantity:
150 Kg
Packing Instructions:
203
Maximum quantity:
75 Kg
Specific instructions:
A145, A167, A802
Proper Shipping Name:
AEROSOLS, FLAMMABLE
Cargo:
Packing Instructions:
Pass.:
SECTION 15 Regulatory information.
15.1. Safety, health and environmental standards and regulations specific for the substance or mixture.
Hazard level for waters Class 1 (D) (Self-classification): slightly hazardous
Seveso category.
8
Restriction applicable to the product or substances contained in accordance with Annex XVIII to EC regulation 1907/2006.
Point 40 (substances that comply with the flammability requirements of Directive 67/548/EEC and are classified as flammable substances, highly
flammable or extremely flammable, even if not listed in part 3 of Annex VI to Regulation (EC) no. 1272/2008.
Directive (EC) no. 75/324 (aerosols)
Mandatory warning label phrases:
Pressurized container. Protect from sunlight. Do not expose to temperatures exceeding 50°C.
Do not pierce or burn, even after use.
Do not spray on an open flame or other ignition source.
Keep out of the reach of children.
Keep away from heat / sparks / open flames / hot surfaces. No smoking.
Substances in the Candidate List (Art. 59 REACH).
None.
Substances subject to authorisation (Annex XIV REACH).
None.
Substances subject to export notification obligations Regulation (EC) 689/2008:
None.
Substances subject to the Rotterdam Convention:
None.
Substances subject to the Stockholm Convention:
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None.
Health Checks
Information unavailable.
Italian Leg. Decree 152/2006 as amended.
Emissions:
TAB. D
Class 5
42.00%
15.2. Chemical safety assessment.
No chemical safety assessment was performed on the mixture and substances contained in the product.
SECTION 16 Further information.
Text for (H) Hazard statements cited in sections 2-3 on the sheet:
Flammable. Gas 1
Flammable gas, category 1
Flammable. Aerosol 1
Flammable aerosol, category 1
Flammable. Liquid 2
Flammable liquid, category 2
H220
Extremely flammable gas.
H222
Extremely flammable aerosol.
H225
Highly flammable liquid and vapour.
Text for (R) risk phrases cited in sections 2-3 on the sheet:
R11
HIGHLY FLAMMABLE.
R12
EXTREMELY FLAMMABLE.
NOTE C: In this case, the supplier must indicate on the label if the substance is a specific isomer or a mixture of isomers. Some organic substances
can be marketed as specific isomer or as a mixture of several isomers.
NOTE U At the time this product is marketed, the gases are classified as "Pressurised Gases" in one of the pertinent groups of compressed gas,
liquefied gas, refrigerated liquefied gas or dissolved gas. The group depends on the physical state in which the gas is packed and is therefore assigned
case by case.
KEY:
- ADR: European agreement concerning the carriage of hazardous goods by road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Concentration that has an effect on 50% of the tested population
- CE NUMBER: ESIS identification number (European Chemical Substances Information System)
- CLP: Regulation (EC) No. 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of Classification and Labelling of Chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulations
- IC50: Concentration of immobilisation that has an effect on 50% of the tested population
- IMDG: International Maritime Dangerous Goods Code
- IMO: International Maritime Organization
- INDEX NUMBER: Identification number in Annex VI to the CLP
- LC50: Lethal concentration 50%
- LD50: Lethal dose 50%
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- OEL: Occupational Exposure Level
- PBT: Persistent, bioaccumulative and toxic according to REACH
- PEC: Predicted environmental concentration
- PEL: Predicted exposure level
- PNEC: Predicted no-effect concentration
- REACH: Regulation (EC) No 1907/2006
- RID: International carriage of dangerous goods by rail
- TLV: Threshold limit value
- TLV CEILING: Concentration that must not be exceeded during any part of the working exposure.
- TWA STEL: Short term exposure limit
- TWA: Time weighed average exposure limit
- VOC: Volatile organic compounds
- vPvB: Very persistent and very bioaccumulative according to the criteria set out by Reach.
GENERAL REFERENCE INFORMATION:
1. Directive (EC) 1999/45/EC as amended
2. Directive (EC) 67/548/EEC as amended
3. European Parliament Directive 1907/2006 (REACH)
4. European Parliament Directive 1272/2008 (CLP)
5. European Parliament Directive 790/2009 (l Atp. CLP)
6. European Parliament Directive 453/2010
7. European Parliament Directive 286/2011 (lI Atp. CLP)
8. The Merck Index. Ed. 10
9. Handling Chemical Safety
10. Niosh - Registry of Toxic Effects of Chemical Substances
11. INRS - Fiche Toxicologique
12. Patty - Industrial Hygiene and Toxicology
13. N.I. Sax - Dangerous properties of Industrial Materials-7 Ed., 1989
14. ECHA Agency Website
Note for users:
The information provided in this Safety Sheet is based on our knowledge at the time the most recent revision was drafted. The user is required to ensure
that the information is complete and appropriate according to the specific use he makes of the product.
This document shall not constitute a guarantee for any specific product features.
As we are unable to control how the product is actually used, the user is obliged to and responsible for complying with all health and safety laws and
regulations in force. All liability and responsibility is disclaimed concerning misuse of the substances.
Appropriate training shall be provided to all workers using chemical products.
SECTIONS AMENDED COMPARED TO THE PREVIOUS EDITION: ALL SECTIONS